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Each crystal has an individual pore size that provides separation benefits. It is clear from the works of Nelson (1933) and also The Minimization of Unwanted [116] Chloride in Ultravioletures book by Linn [117] that all these zeolites have the structure of 0 2 3 4 5 6 7. A disadvantage of zeolites is the fact that the surface is relatively weak and that the crystals are easily damaged. This comes from lack of bulk strength. In reality this minimizes the problem of weight because the surface can be weakened with the use of sodium cations. Zeolites are known to be silver catalysts, and some zeolites contain charges on their surfaces. These charges may lead to the production of ozone. The molecular structure of zeolites may be changed through, for example, the introduction of other metallic species into the manufacture of zeolites. The substitution of some elements in the lattice of zeolites reduces the number of cations present in the solid and, thus, increases the space between the framework and the adsorbent.
Unfortunately, a number of disadvantages, such as the negative charge of faujasite and the high density of silver zeolite, hinder the application of these materials. Scientists have endeavored to create new zeolites with as little negative charge and as high adsorbability as possible. The adsorption characteristics of these zeolites are measured by the combination of adsorption and desorption of bromine. Accounting for the relative rate of adsorption and the rate of desorption gives a measure of the adsorption capacity.
The most widely accepted classification of the zeolites is based on their silica, alumina and water content, which can be expressed by the following formula: SiO2Al 2 O3 W 2 O3. The hydroxyl groups of the silica are believed to take part, not only in the adsorption of the molecules to be separated, but also in the isolation of the pure adsorbate. The basic principle of the separation is replacement of the adsorbent particle with a molecule that is smaller than the diameter of the pore in the adsorbent. d2c66b5586
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